in that case you need to locate the function which set the AES key and this is a job enough simple because you can retrieve the s-boxes (practically the array with the constants) with my signsrch tool (
http://aluigi.org/mytoolz.htm#signsrch) and so with a disassembler you see the function which calls/uses that s-box.
if the key is fixed and you are lucky you could even find the key there in the disassembled code, otherwise you need to use the debugger.
in that case the key can be fixed (like happen almost ever) or it's calculated at runtime using some unique fields of the computer (mac address of the interfaces, productid of windows, volumeid of c: and so on).